The “Connection” tab needs reordering as a minimum change.
The first two sections are hardly ever touched (Being “Connection” and “Modem”).
However the “Outlook Anywhere” is used a lot, so that should be the first section.

PS: On the “Microsoft Exchange Proxy Settings” form, we need button under the first textbox “Populate Settings From Mail Server”(or is there a security reason this could not be done).

Figure: Settings are hardly ever touched